This paper describes a new method for calculating the solvation pressure that acts between solid surfaces when the surfaces approach each other to within a very small distance in a liquid medium. Solvation pressure is calculated by solving the transformed Ornstein-Zernike equation for hard-spheres in a two-phase system with Perram’s method and using the Derjaguin approximation. Furthermore, the authors apply the new method to the elastohydrodynamic lubrication problem in which the film thickness is very small and solvation force and van der Waals force cannot be neglected. It will be shown that the calculation results agree well with experimental data. The results are then compared with two conventional solvation pressure models proposed so far, namely, Chan and Horn’s model, and, Jang and Tichy’s model. It is found that these two models neglect the elastic deformation of solid surface when obtaining the experimental parameter used in their models; thus they overestimate the solvation pressure resulting in the prediction of larger film thickness than the experiments.

1.
Alder
B. J.
,
Frankel
S. P.
,
Lewinson
V. A.
,
1955
, “
Radial Distribution Function Calculated by the Monte-Carlo Method for a Hard Sphere Fluid
,”
Journal of Chemical Physics
, Vol.
23
, pp.
417
419
.
2.
Baxter
R. J.
,
1970
, “
Ornstein-Zernike Relation and Percus-Yevick Approximation for Fluid Mixtures
,”
Journal of Chemical Physics
, Vol.
52
, pp.
4559
4562
.
3.
Bitsanis
I.
,
Magda
J. J.
,
Trrell
M.
, and
Davis
H. T.
,
1987
, “
Molecular Dynamics of Flow in Micropores
,”
Journal of Chemical Physics
, Vol.
87
, pp.
1733
1750
.
4.
Carson
G.
,
Hu
H.-W.
, and
Granick
S.
,
1992
, “
Molecular Tribology of Fluid Lubrication: Shear Thinning
,”
STLE Tribology Transactions
, Vol.
35
, pp.
405
410
.
5.
Chan
D. Y. C.
, and
Horn
R. G.
,
1985
, “
The Drainage of Thin Liquid Films between Solid Surfaces
,”
Journal of Chemical Physics
, Vol.
83
, pp.
5311
5324
.
6.
Chittenden
R. J.
,
Dowson
D.
,
Dunn
J. F.
, and
Taylor
C. M.
,
1985
, “
A Theoretical Analysis if the Isothermal Elastohydrodynamic Lubrication of Concentrated Contacts I. Direction of Lubricant Entrainment Coincident with the Major Axis of the Hertzian Contact Ellipse
,”
Proceedings of the Royal Society of London
, Series A, Vol.
397
, pp.
245
269
.
7.
Christenson
H. K.
,
1983
, “
Experimental Measurements of Solvation Forces in Nonpolar Liquids
,”
Journal of Chemical Physics
, Vol.
78
, pp.
6906
6913
.
8.
Christenson
H. K.
,
Horn
R. G.
, and
Israelachvili
J. N.
,
1982
, “
Measurement of Forces Due to Structure in Hydrocarbon Liquids
,”
Journal of Colloid and Interface Science
, Vol.
88
, pp.
79
88
.
9.
de Bruyne
F. A.
, and
Bogy
D. B.
,
1994
, “
Numerical Simulation of the Lubrication of the Head-Disk Interface Using a Non-Newtonian Fluid
,”
ASME JOURNAL OF TRIBOLOGY
, Vol.
116
, pp.
541
548
.
10.
Dowson, D., and Higginson, G. R., 1977, “Elasto-Hydrodynamic Lubrication,” SI edition, Pergamon Press.
11.
Esfahanian
M.
, and
Hamrock
B. J.
,
1991
, “
Fluid-Film Lubrication Regimes Revisited
,”
STLE Tribology Transactions
, Vol.
34
, pp.
628
632
.
12.
Evans
H. P.
, and
Snidle
R. W.
,
1981
, “
The Isothermal Elastohydrodynamic Lubrication of Spheres
,”
ASME JOURNAL OF LUBRICATION TECHNOLOGY
, Vol.
103
, pp.
547
557
.
13.
Gaines
G. L.
,
1957
, “
The Ion-Exchange Properties of Muscovite Mica
,”
Journal of Physical Chemistry
, Vol.
61
, pp.
1408
1413
.
14.
Gee
M. L.
,
McGuiggan
P. M.
,
Israelachvili
J. N.
, and
Homola
A. M.
,
1990
, “
Liquid to Solidlike Transition of Molecularly Thin Films under Shear
,”
Journal of Chemical Physics
, Vol.
93
, pp.
1895
1906
.
15.
Georges
J. M.
,
Millot
S.
,
Loubet
J. L.
, and
Tonk
A.
,
1993
(a), “
Drainage of Thin Liquid Films between Relatively Smooth Surfaces
,”
Journal of Chemical Physics
, Vol.
98
, pp.
7345
7360
.
16.
Georges, J. M., Millot, S., Loubet, J. L., Tonk, A., and Mazuyer, D., 1993(b), “Surface Roughness and Squeezed Films at Molecular Level,” Proceedings of the 19th Leeds-Lyon Symposium on Tribology, pp. 443–452.
17.
Georges, J. M., Tonk, A., Mazuyer, D., 1995, “Static and Dynamic Frictions of Compressed Polymer Layers,” Synopses of International Tribology Conference’, 95, Yokohama, pp. 1.
18.
Granick
S.
,
1991
, “
Motions and Relaxations of Confined Liquids
,”
Science
, Vol.
253
, pp.
1374
1379
.
19.
Granick
S.
, and
Hu
H.-W.
,
1994
, “
Nanorheology of Confined Polymer Melts. I. Linear Shear Response at Strongly Adsorbing Surfaces
,”
Langmuir
, Vol.
10
, pp.
3857
3866
.
20.
Granick
S.
,
Demirel
A. L.
,
Cai
L. L.
, and
Peanasky
J.
,
1995
, “
Nanorheology of Confined Liquids and Block Copolymers
,”
Israel Journal of Chemistry
, Vol.
35
, pp.
75
84
.
21.
Guangteng, G., and Spikes, H. A., 1994, “Behavior of Lubricants in the Mixed Elastohydrodynamic Regime,” presented at the 21st Leeds-Lyon Symposium on Tribology.
22.
Guangteng, G., and Spikes, H. A., 1995, “Boundary Film Formation by Lubricant Base Fluids,” presented at the 50th STLE Annual Meeting in Chicago, No. 95-NP-7D-3.
23.
Hamrock
B. J.
, and
Dowson
D.
,
1976
, “
Isothermal Elastohydrodynamic Lubrication of Point Contacts Part 1—Theoretical Formulation
,”
ASME JOURNAL OF LUBRICATION TECHNOLOGY
, Vol.
98
, pp.
223
229
.
24.
Hamrock, B. J., and Dowson, D., 1978, “Minimum Film Thickness in Elliptical Contacts for Different Regimes of Fluid Film Lubrication,” Proceedings of the 5th Leeds-Lyon Symposium on Tribology, pp. 22–27.
25.
Henderson
D.
, and
Lozada-Cassou
M.
,
1986
, “
A Simple Theory for the Force between Spheres Immersed in a Fluid
,”
Journal of Colloid and Interface Science
, Vol.
114
, pp.
180
183
.
26.
Heyes
D. M.
,
Kim
J. J.
,
Montrose
C. J.
, and
Litovitz
T. A.
,
1980
, “
Time Dependent Nonlinear Shear Stress Effects in Simple Liquids: A Molecular Dynamics Study
,”
Journal of Chemical Physics
, Vol.
73
, pp.
3987
3996
.
27.
Homola, A. M., 1991, “The Role of Interfacial Forces and Lubrication in Thin-Film Magnetic Media,” Advances in Information Storage System, Vol. 1, pp. 279–308.
28.
Homola
A. M.
,
Israelachvili
J. N.
,
Gee
M. L.
, and
McGuiggan
P. M.
,
1989
, “
Measurement of and Relation between the Adhesion and Friction of Two Surfaces Separated by Molecularly Thin Liquid Films
,”
ASME JOURNAL OF TRIBOLOGY
, Vol.
111
, pp.
675
682
.
29.
Horn
R. G.
, and
Israelachvili
J. N.
,
1981
, “
Direct Measurement of Structural Forces between Two Surfaces in a Nonpolar Liquid
,”
Journal of Chemical Physics
, Vol.
75
, pp.
1400
1411
.
30.
Ikeda
Y.
, and
Tago
K.
,
1995
, “
Tribological Study on Molecularly Thin Films Using Non-Equilibrium Molecular Dynamics
,”
JAST Journal of Japanese Society of Tribologists
, Vol.
40
, pp.
253
259
.
31.
Israelachvili
J. N.
,
1972
, “
The Calculation of van der Waals Dispersion Forces between Macroscopic Bodies
,”
Proceedings of the Royal Society of London
, Series A, Vol.
331
, pp.
39
55
.
32.
Israelachvili, J. N., 1992, “Intermolecular and Surface Forces,” 2nd edition, Academic Press.
33.
Israelachvili
J. N.
,
McGuiggan
P. M.
, and
Homola
A. M.
,
1988
, “
Dynamic Properties of Molecularly Thin Liquid Films
,”
Science
, Vol.
240
, pp.
189
191
.
34.
Jang
S.
, and
Tichy
J. A.
,
1995
, “
Rheological Models for Thin Film EHL Contacts
,”
ASME JOURNAL OF TRIBOLOGY
, Vol.
117
, pp.
22
28
.
35.
Johnston
G. J.
,
Wayte
R.
, and
Spikes
H. A.
,
1991
, “
The Measurement and Study of Very Thin Lubricant Films in Concentrated Contacts
,”
STLE Tribology Transactions
, Vol.
34
, pp.
187
194
.
36.
Lifshitz
E. M.
,
1956
, “
The Theory of Molecular Attractive Forces between Solids
,”
Soviet Physics, JETP
, Vol.
2
, pp.
73
83
.
37.
Lin
J. F.
, and
Chu
H. Y.
,
1991
, “
A Numerical Solution for Calculating Elastic Deformation in Elliptical-Contact EHL of Rough Surface
,”
ASME JOURNAL OF TRIBOLOGY
, Vol.
113
, pp.
12
21
.
38.
Luo, J. B., Wen, S. Z., and Cao, N. J., 1995, “Study on the Characteristics of Lubricant Film at Nanometer Scale,” Synopses of International Tribology Conference ’95, Yokohama, pp. 2.
39.
Matsuoka, H., and Kato, T., 1996, “Discrete Nature of Ultrathin Lubrication Film Between Mica Surfaces,” ASME JOURNAL OF TRIBOLOGY, to be published.
40.
Ornstein, L. S., and Zernike, F., 1914, “Accidental Deviations of Density and Opalescence at the Critical Point of a Single Substance,” Proceedings of the Royal Academy, Amsterdam, Vol. 17, pp. 793–806.
41.
Peachey
J.
,
van Alsten
J.
, and
Granick
S.
,
1991
, “
Design of an Apparatus to Measure the Shear Response of Ultrathin Liquid Films
,”
Review in Scientific Instruments
, Vol.
62
, pp.
463
473
.
42.
Percus
J. K.
, and
Yevick
G. J.
,
1958
, “
Analysis of Classical Statistical Mechanics by Means of Collective Coordinates
,”
Physical Review
, Vol.
110
, pp.
1
13
.
43.
Perram
J. W.
,
1975
, “
Hard Sphere Correlation Functions in the Percus-Yevick Approximation
,”
Molecular Physics
, Vol.
30
, pp.
1505
1509
.
44.
Prieve
D. C.
, and
Russel
W. B.
,
1988
, “
Simplified Predictions of Hamaker Constants from Lifshitz Theory
,”
Journal of Colloid and Interface Science
, Vol.
125
, pp.
1
13
.
45.
Smeeth, M., Spikes, H. A., and Gunsel, S., 1995(a), “The Formation of Viscous Surface Films by Polymer Solutions: Boundary or Elastohydrodynamic Lubrication?,” presented at the 50th STLE Annual Meeting in Chicago, No. 95-NP-7D-2.
46.
Smeeth, M., Spikes, H. A., and Gunsel, S., 1995(b), “Boundary Film Formation by Viscosity Index Improvers,” presented at the STLE/ASME Tribology Conference in Florida, No. 95-TC-3C-1.
47.
Smith
W. R.
, and
Henderson
D.
,
1970
, “
Analytical Representation of the Percus-Yevick Hard-Sphere Radial Distribution Function
,”
Molecular Physics
, Vol.
19
, pp.
411
415
.
48.
Snook
I.
, and
van Megen
W.
,
1979
, “
Structure of Dense Liquids at Solid Interfaces
,”
Journal of Chemical Physics
, Vol.
70
, pp.
3099
3105
.
49.
Snook
I. K.
, and
van Megen
W.
,
1980
, “
Solvation Forces in Simple Dense Fluids. I
,”
Journal of Chemical Physics
, Vol.
72
, pp.
2907
2913
.
50.
Snook
I. K.
, and
van Megen
W.
,
1981
, “
Calculation of Solvation Forces between Solid Particles Immersed in a Simple Liquid
,”
Journal of Chemical Society, Faraday Transactions II
, Vol.
77
, pp.
181
190
.
51.
Spikes, H., 1995, “The Thickness and Rheology of Boundary Lubricating Films,” Synopses of International Tribology Conference ’95, Yokohama, pp. 3.
52.
Tarazona
P.
, and
Vicente
L.
,
1985
, “
A Model for Density Oscillations in Liquids between Solid Walls
,”
Molecular Physics
, Vol.
56
, pp.
557
572
.
53.
Throop
G. J.
, and
Bearman
R. J.
,
1965
, “
Numerical Solutions of the Percus-Yevick Equation for the Hard-Sphere Potential
,”
Journal of Chemical Physics
, Vol.
42
, pp.
2408
2411
.
54.
Tichy
J. A.
,
1995
(a), “
Modeling of Thin Film Lubrication
,”
STLE Tribology Transactions
, Vol.
38
, pp.
108
118
.
55.
Tichy
J. A.
,
1995
(b), “
A Surface Layer Model for Thin Film Lubrication
,”
STLE Tribology Transactions
, Vol.
38
, pp.
577
582
.
56.
Tichy
J. A.
,
1995
(c), “
A Porous Media Model for Thin Film Lubrication
,”
ASME JOURNAL OF TRIBOLOGY
, Vol.
117
, pp.
16
21
.
57.
van Alsten
J.
, and
Granick
S.
,
1988
, “
Molecular Tribometry of Ultrathin Liquid Films
,”
Physical Review Letters
, Vol.
61
, pp.
2570
2573
.
58.
van Alsten
J.
, and
Granick
S.
,
1990
, “
Tribology Studied Using Atomically Smooth Surfaces
,”
STLE Tribology Transactions
, Vol.
33
, pp.
436
446
.
59.
van Megen
W.
, and
Snook
I.
,
1979
, “
Solvent Structure and Solvation Forces between Solid Bodies
,”
Journal of Chemical Society, Faraday Transactions II
, Vol.
75
, pp.
1095
1102
.
60.
Venner
C. H.
, and
ten Napel
W. E.
,
1992
(a), “
Multilevel Solution of the Elastohydrodynamically Lubricated Circular Contact Problem Part 1: Theory and Numerical Argorithm
,”
Wear
, Vol.
152
, pp.
351
367
.
61.
Venner
C. H.
, and
ten Napel
W. E.
,
1992
(b), “
Multilevel Solution of the Elastohydrodynamically Lubricated Circular Contact Problem Part 2: Smooth Surface Results
,”
Wear
, Vol.
152
, pp.
369
381
.
62.
Wertheim
M. S.
,
1963
, “
Exact Solution of the Percus-Yevick Integral Equation for Hard Spheres
,”
Physical Review Letters
, Vol.
10
, pp.
321
323
.
63.
Wertheim
M. S.
,
1964
, “
Analytic Solution of the Percus-Yevick Equation
,”
Journal of Mathematical Physics
, Vol.
5
, pp.
643
651
.
64.
White
L. R.
,
1983
, “
On the Deryaguin Approximation for the Interaction of Macrobodies
,”
Journal of Colloid and Interface Science
, Vol.
95
, pp.
286
288
.
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