Over the past decade, we have developed deterministic models for predicting materials damage due to stress corrosion cracking (SCC) in boiling water reactor (BWR) primary coolant circuits. These steady-state models have been applied to fixed state points of reactor operation to yield electrochemical corrosion potential (ECP) and crack growth rate (CGR) predictions. However, damage is cumulative, so that prediction of the extent of damage at any given time must integrate crack growth rate over the history of the plant. In this paper, we describe the use of the REMAIN code to predict the accumulated damage functions for major components in the coolant circuit of a typical BWR that employs internal coolant pumps. As an example, the effect of relatively small amounts of hydrogen added to the feedwater (e.g., 0.5 ppm) on the development of damage from a 0.197-in. (0.5-cm) intergranular crack located at the exit of an internal pump was analyzed. It is predicted that hydrogen additions to the feedwater will effectively suppress further growth of the crack. We also report the first predictions of the accumulation of damage from SCC for a variable power operating cycle. We predict that the benefits of hydrogen water chemistry (HWC), as indicated by the behavior of a single crack under constant environmental conditions, are significantly muted by changes in reactor power. [S0094-9930(00)01301-9]

1.
Ibe
,
E.
,
1987
, “
Radiolytic Environments in Boiling Water Reactor Cores
,”
J. Nucl. Sci. Technol.
,
24
, pp.
220
226
.
2.
Ishigure
,
K.
,
Takagi
,
J.
, and
Shiraishi
,
H.
,
1987
, “
Hydrogen Injection in BWR and Related Radiation Chemistry
,”
Radiat. Phys. Chem.
,
29
, pp.
195
199
.
3.
Ruiz, C. P. et al., 1989, “Modeling Hydrogen Water Chemistry for BWR Applications,” EPRI-NP-6386, Electric Power Research Institute, Palo Alto, CA.
4.
Yeh
,
T. K.
,
Macdonald
,
D. D.
, and
Motta
,
A. T.
,
1995
, “
Modeling Water Chemistry, Electrochemical Corrosion Potential, and Crack Growth Rate in the Boiling Water Reactor Heat Transport Circuits–Part I: The DAMAGE-PREDICTOR Algorithm
,”
Nucl. Sci. Eng.
,
121
, pp.
468
482
.
5.
Yeh
,
T. K.
,
Macdonald
,
D. D.
, and
Motta
,
A. T.
,
1996
, “
Modeling Water Chemistry, Electrochemical Corrosion Potential, and Crack Growth Rate in the Boiling Water Reactor Heat Transport Circuits–Part II: Simulation of Operating Reactors
,”
Nucl. Sci. Eng.
,
123
, pp.
295
304
.
6.
Yeh
,
T. K.
,
Macdonald
,
D. D.
, and
Motta
,
A. T.
,
1996
, “
Modeling Water Chemistry, Electrochemical Corrosion Potential, and Crack Growth Rate in the Boiling Water Reactor Heat Transport Circuits–Part III: Effect of Reactor Power Level
,”
Nucl. Sci. Eng.
,
123
, pp.
305
316
.
7.
Macdonald
,
D. D.
, and
Urquidi-Macdonald
,
M.
,
1990
, “
Thin Layer Mixed Potential Model for the Corrosion of High-Level Nuclear Waste Canisters
,”
Corrosion (Houston)
,
46
, pp.
380
390
.
8.
Macdonald, D. D. et al., 1994, “Estimation of Corrosion Potentials in the Heat Transport Circuits of LWRs,” Proceedings, International Conference in Chemistry in Water Reactors: Operating Experience & New Developments, Nice, France.
9.
Macdonald
,
D. D.
,
1992
, “
Viability of Hydrogen Water Chemistry for Protecting In-Vessel Components of Boiling Water Reactors
,”
Corrosion (Houston)
,
48
, pp.
194
205
.
10.
Macdonald
,
D. D.
, and
Urquidi-Macdonald
,
M.
,
1991
, “
A Coupled Environment Model for Stress Corrosion Cracking in Sensitized Type 304 Stainless Steel in LWR Environments
,”
Corros. Sci.
,
32
, pp.
51
81
.
11.
Macdonald, D. D., and Urquidi-Macdonald, M., 1992, “An Advanced Coupled Environment Fracture Mode for Predicting Crack Growth Rates,” Proceedings, TMS Parkins Symposium on the Fundamental Aspects of Stress Corrosion Cracking, TMS, Warrendale, PA, pp. 443–455.
12.
Macdonald
,
D. D.
,
Lu
,
P. C.
,
Urquidi-Macdonald
,
M.
, and
Yeh
,
T. K.
,
1996
, “
Theoretical Estimation of Crack Growth Rates in Type 304 Stainless Steel in BWR Coolant Environments
,”
Corrosion (Houston)
,
52
, pp.
768
785
.
13.
Macdonald
,
D. D.
,
1996
, “
On the Modeling of Stress Corrosion Cracking in Iron and Nickel Base Alloys in High Temperature Aqueous Environments
,”
Corros. Sci.
,
38
, pp.
1003
1010
.
14.
Indig
,
M.
, and
Nelson
,
J. L.
,
1991
, “
Electrochemical Measurements and Modeling Predictions in Boiling Water Reactors Under Various Operating Conditions
,”
Corrosion (Houston)
,
47
, pp.
202
209
.
15.
Balachov, I., and D. D. Macdonald, 1999, “Modeling Hydrogen Water Chemistry at the Liebstadt BWR,” in preparation.
16.
Macdonald, D. D., and Kriksunov, L., 1997, “Flow Rate Dependence of Localized Corrosion Processes in Thermal Power Plants,” Advances in Electrochemical Science and Engineering, 5, John Wiley & Sons, New York, NY, pp. 125–193.
17.
Manahan
,
M. P.
,
Macdonald
,
D. D.
, and
Peterson
,
A. J.
,
1995
, “
Determination of the Fate of the Current in the Stress-Corrosion Cracking of Sensitized Type 304SS in High Temperature Aqueous Systems
,”
Corros. Sci.
,
37
, pp.
189
208
.
18.
Niedrach
,
L.
,
1991
, “
Effect of Palladium Coatings on the Corrosion Potential of Stainless Steel in High Temperature Water Containing Dissolved Hydrogen and Oxygen
,”
Corrosion (Houston)
,
47
, pp.
162
169
.
19.
Kim
,
Y. J.
,
Andresen
,
P. L.
,
Gray
,
D. M.
,
Lau
,
Y.-C.
, and
Offer
,
H. P.
,
1996
, “
Corrosion Potential Behavior in High Temperature Water of Noble Metal-Doped Alloy Coatings Deposited by Underwater Thermal Spray
,”
Corrosion (Houston)
,
52
, pp.
440
446
.
20.
Kim
,
Y.-J.
,
Niedrach
,
L. W.
, and
Andresen
,
P. L.
,
1996
, “
Corrosion Potential Behavior of Noble Metal-Modified Alloys in High Temperature Water
,”
Corrosion (Houston)
,
52
, pp.
738
743
.
21.
Yeh, T.-K., Yu, M.-S., and Macdonald, D. D., 1997, “The Effect of Catalytic Coatings on IGSCC Mitigation for Boiling Water Reactors Operated Under Hydrogen Water Chemistry,” Proceedings 8th International Symposium on the Environmental Degradation of Materials in Nuclear Power Systems—Water Reactors, NACE International, Houston, TX, 1, pp. 551–558.
22.
Zhou
,
X.
,
Balachov
,
I.
, and
Macdonald
,
D. D.
,
1998
, “
The Effect of Dielectric Coatings on Sensitized Type 304 SS in High Temperature Dilute Sodium Sulfate Solution
,”
Corros. Sci.
,
40
, pp.
1349
1362
.
23.
Liu
,
C.
, and
Macdonald
,
D. D.
,
1997
, “
Prediction of Failures of Low Pressure Steam Turbine Disks
,”
ASME J. Pressure Vessel Technol.
,
119
, pp.
393
400
.
24.
Englehardt
,
G.
,
Urquidi-Macdonald
,
M.
, and
Macdonald
,
D. D.
,
1997
, “
A Simplified Method for Estimating Corrosion Cavity Growth Rates
,”
Corros. Sci.
,
39
, pp.
419
441
.
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