For improved efficiency and reduced emissions, the future power plants need to operate at high temperatures and pressures, which however are limited by the durability of conventional materials such as ferritic steels. Steam oxidation of a number of coatings (Al slurries, thermal spraying, chemical vapor deposition siliconizing, and nickel plating) has demonstrated the feasibility of coatings to improve oxidation resistance. Al slurry coatings combine good high-temperature oxidation resistance through the growth of an Al2O3 layer and the possibility to apply the coating on an industrial scale at moderate cost. This work aimed to test the oxidation performance of coatings and reference alloys in ultra-supercritical (USC) water. The tested materials included Al slurry coating on ferritic 9%Cr steel and nickel-based A263 substrates, and bulk P92, MARBN, and A263 alloys as reference specimens. Oxidation resistance was tested by exposure to flowing supercritical water (SCW) with 125 ppb dissolved oxygen at 650°C (1202°F)/25MPa (3625 psi) up to 1000 hr.

References

1.
Viswanathan
,
R.
,
Purgert
,
R.
, and
Rawls
,
P.
,
2008
, “
Coal-Fired Power Materials
,”
Adv. Mater. Processes
,
166
(
8
), pp.
47
49
.
2.
Natesan
,
K.
, and
Park
,
J. H.
,
2007
, “
Fireside and Steamside Corrosion of Alloys for USC Plants
,”
Int. J. Hydrogen Energy
,
32
(
16
), pp.
3689
3697
. 0360-319910.1016/j.ijhydene.2006.08.038
3.
Ennis
,
P. J.
, and
Quadakkers
,
W. J.
,
2007
, “
Implications of Steam Oxidation for the Service Life of High-Strength Martensitic Steel Components in High-Temperature Plant
,”
Int. J. Press. Vessels Pip.
,
84
(
1–2
), pp.
82
87
. 0308-016110.1016/j.ijpvp.2006.09.008
4.
Zurek
,
J.
,
Wessel
,
E.
,
Niewolak
,
L.
,
Schmitz
,
F.
,
Kern
,
T.-U.
,
Singheiser
,
L.
, and
Quadakkers
,
W. J.
,
2004
, “
Anomalous Temperature-Dependence of Oxidation Kinetics During Steam Oxidation of Ferritic Steels in the Temperature Range 550–650°C
,”
Corros. Sci.
,
46
(
9
), pp.
2301
2317
. 0010-938X10.1016/j.corsci.2004.01.010
5.
Laverde
,
D.
,
Gomez-Acebo
,
T.
, and
Castro
,
F.
,
2004
, “
Continuous and Cyclic Oxidation of T91 Ferritic Steel Under Steam
,”
Corros. Sci.
,
46
(
3
), pp.
613
631
. 0010-938X10.1016/S0010-938X(03)00173-2
6.
Agüero
,
A.
,
Muelas
,
R.
,
Pastor
,
A.
, and
Osgerby
,
S.
,
2005
, “
Long Exposure Steam Oxidation Testing and Mechanical Properties of Slurry Aluminide Coatings for Steam Turbine Components
,”
Surf. Coat. Technol.
,
200
(
5–6
), pp.
1219
1224
.10.1016/j.surfcoat.2005.07.080
7.
Tamarin
,
Y.
,
2002
,
Protective Coatings for Turbine Blades
,
ASM International
,
Materials Park, OH
,
247
pp.
8.
Vaillant
,
J. C.
,
Vandenberghe
,
B.
,
Hahn
,
B.
,
Heuser
,
H.
, and
Jochum
,
C.
,
2008
, “
T/P23, 24, 911 and 92: New Grades for Advanced Coal-Fired Power Plants—Properties and Experience
,”
Int. J. Press. Vessels Pip.
,
85
(
1–2
), pp.
38
46
. 0308-016110.1016/j.ijpvp.2007.06.011
9.
Pohja
,
R.
,
Holmström
,
S.
,
Nurmela
,
A.
, and
Moilanen
,
P.
,
2014
, “
A Study of Creep-Fatigue Interaction in the Nickel-Base Superalloy 263
,”
10th Liege Conference: Materials for Advanced Power Engineering 2014
,
J.
Lecomte-Beckers
,
,
O.
Dedry
,
J.
Oakey
, and
B.
Kuhn
, eds.,
Forschungszentrum Jülich, Energy & Environment
,
Jülich, Germany
, Vol.
234
, pp.
678
687
.
10.
Toivonen
,
A.
, and
Penttilä
,
S.
,
2013
, “
General Corrosion and SCC Tests on ODS Steels in Supercritical Water
,”
Baltica IX. International Conference on Life Management and Maintenance for Power Plants
,
Espoo, Finland
,
VTT Technical Research Centre of Finland
,
Espoo, Finland
, pp.
174
193
.
11.
Ehlers
,
J.
,
Young
,
D. J.
,
Smaardijk
,
E. J.
,
Tyagi
,
A. K.
,
Penkalla
,
H. J.
,
Singheiser
,
L.
, and
Quadakkers
,
W. J.
,
2006
, “
Enhanced Oxidation of the 9%Cr Steel P91 in Water Vapour Containing Environments
,”
Corros. Sci.
,
48
(
11
), pp.
3428
3454
. 0010-938X10.1016/j.corsci.2006.02.002
12.
Goral
,
M.
,
Swadzba
,
L.
,
Moskal
,
G.
,
Jarczyk
,
G.
, and
Aguilar
,
J.
,
2011
, “
Diffusion Aluminide Coatings for TiAl Intermetallic Turbine Blades
,”
Intermetallics
,
19
(
5
), pp.
744
747
. 0966-979510.1016/j.intermet.2010.12.015
13.
Cabot
,
A.
,
Puntes
,
V. F.
,
Shevchenko
,
E.
,
Yin
,
Y.
,
Balcelles
,
L.
,
Marcus
,
M. A.
,
Hughes
,
S. M.
, and
Alivisatos
,
A. P.
,
2007
, “
Vacancy Coalescence During Oxidation of Iron Nanoparticles
,”
J. Am. Chem. Soc.
,
129
(
34
), pp.
10358
10360
.10.1021/ja072574a
14.
Vaari
,
J.
,
2015
, “
Molecular Dynamics Simulations of Vacancy Diffusion in Chromium(III) Oxide, Hematite, Magnetite and Chromite
,”
Solid State Ionics
,
270
, pp.
10
17
. 0167-273810.1016/j.ssi.2014.11.027
15.
Allen
,
G. C.
,
Dyke
,
J. M.
,
Harris
,
S. J.
, and
Morris
,
A.
,
1988
, “
A Surface Study of the Oxidation of Type 304L Stainless Steels at 600 K in Air
,”
Oxid. Met.
,
29
, pp.
391
408
. 0030-770X10.1007/BF00666841
16.
Agüero
,
A.
,
Gutiérriez
,
M.
, and
González
,
V.
,
2008
, “
Deposition Process of Slurry Iron Aluminide Coatings
,”
Mater. High Temp.
,
25
(
4
), pp.
257
265
. 0960-340910.3184/096034008X388812
17.
Van Nieuwenhove
,
R.
,
Balak
,
J.
,
Toivonen
,
A.
,
Penttilä
,
S.
, and
Ehrnsten
,
U.
,
2013
, “
Investigation of Coatings, Applied by PVD, for the Corrosion Protection of Materials in Supercritical Water
,”
Proceedings of 6th International Symposium on Supercritical Water-Cooled Reactors (ISSCWR-6)
,
Shenzhen, Guangdong, China
,
Mar. 3–7
, pp.
1
12
.
18.
Rasmussen
,
A. J.
,
Agüero
,
A.
,
Gutierrez
,
M.
, and
Landeira Østergård
,
M. J.
,
2008
, “
Microstructures of Thin and Thick Slurry Aluminide Coatings on Inconel 690
,”
Surf. Coat. Technol.
,
202
(
8
), pp.
1479
1485
.10.1016/j.surfcoat.2007.06.056
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