Abstract

The need for the replacement of cadmium, indium, and tellurium in their compounds for sensor applications is a novel study. The copper zinc tin sulfide (Cu2ZnSnS4) thin films were synthesized from Cu (99.99%), Sn (99.99%), and Zn (99.99%) using the thermal evaporation method. The same volumetric parameters were maintained throughout the synthesis process. The films were further irradiated using an isotope of cesium-137 (Cs-137) from a gamma source at different doses (0–0.6 kGy) and dose rates of 0.1007 Gy/h at room temperature. Both the pristine (0 kGy) and irradiated (0.1, 0.3, and 0.6 kGy) films were characterized with a Raman spectroscope, a field emission scanning electron microscope (FESEM) with the JEOL JSM-7600F model, energy dispersive X-rays (EDX), an ultraviolet–visible–near infrared (UV–Vis–NIR) spectroscope, and four-point probe techniques. The Raman results confirmed that all the films for both pristine and irradiated films have a main and secondary phases. The EDX results showed that the pristine and 0.1 kGy films were Cu-rich films, while the 0.3 kGy and 0.6 kGy films turned out to be Zn-rich films with an increase in gamma radiation dose. The optical properties of all the films showed also that the band gap decreased from 1.6 to 1.48±0.03 eV for the pristine and irradiated films, while the electrical resistivity results decreased as the gamma radiation dose increased. However, as the structural, optical, and electrical properties of the Cu2ZnSnS4 thin films responded linearly with the increasing gamma radiation dose, this suggests the usefulness and possibility of designing a new solid-state sensor for dosimetry applications to replace cadmium telluride (CdTe) and copper indium gallium sulfide (CIGS) thin films.

References

1.
Damulira
,
E.
,
2022
, “
Radiation Dosimetry in Medicine Using II-VI Semiconductors
,”
J. Radiat. Res. Appl. Sci.
,
15
(
3
), pp.
72
82
.10.1016/j.jrras.2022.06.001
2.
Iwata
,
T.
,
Kinashi
,
K.
,
Doan
,
H. N.
,
Vo
,
P. P.
,
Sakai
,
W.
, and
Tsutsumi
,
N.
,
2019
, “
Leuco-Based Composite Resin Dosimeter Film
,”
Am. Chem. Soc. Omega
,
4
(
6
), pp.
9946
9951
.10.1021/acsomega.9b00435
3.
Oberoi
,
P.
,
Maurya
,
C.
, and
Mahanwar
,
P.
,
2019
, “
Effect of Gamma Irradiation Dose on Phthalate Free Polyvinyl Chloride (PVC) Dyed Thin Film Dosimeter
,”
J. Mater. Environ. Sci.
,
10
(
6
), pp.
533
542
.https://www.jmaterenvironsci.com/Document/vol10/vol10_N6/56-JMES-Oberoi-2019.pdf
4.
Sharma
,
S. L.
, and
Maity
,
T. K.
,
2011
, “
Effect of Gamma Radiation on Electrical and Optical Properties of (TeO2)0·9 (In2O3)0·1 Thin Films
,”
Bull. Mater. Sci.
,
34
(
1
), pp.
61
69
.10.1007/s12034-011-0027-2
5.
Maity
,
T. K.
,
Sudha
,
A.
,
Sharma
,
S. L.
,
Sharma
,
S. D.
, and
Chourasiya
,
G.
,
2015
, “
High Sensitivity Gamma Radiation Dosimetry Using (In2O3)0.1 (TeO2)0.9 Thin Films
,”
J. Radiat. Prot. Environ.
,
38
(
4
), pp.
135
138
.10.4103/0972-0464.176156
6.
Idris
,
M. M.
,
Olarinoye
,
I. O.
,
Kolo
,
M. T.
,
Ibrahim
,
S. O.
, and
Audu
,
J. K.
,
2023
, “
High Energy X-Ray Dosimetry Using (ZnO)0.2(TeO2)0.8 Thin Film Based Real-Time X-Ray
,”
Non-Metallic Mater. Sci.
,
5
(
1
), pp.
4
13
.10.30564/nmms.v5i1.5369
7.
Ali
,
A. M. A.
,
Ahmed
,
N. M.
,
Mohammad
,
S. M.
,
Sabah
,
F. A.
,
Kabaa
,
E.
,
Alsadig
,
A.
, and
Sulieman
,
A.
,
2019
, “
Effect of Gamma Irradiation Dose on the Structure and pH Sensitivity of ITO Thin Films in Extended Gate Field Effect Transistor
,”
Results Phys.
,
12
, pp.
615
622
.10.1016/j.rinp.2018.10.066
8.
Obasi
,
C. O.
,
Isah
,
K. U.
,
Yabagi
,
J. A.
, and
Kimpa
,
M. I.
,
2022
, “
Influence of Gamma Radiation on Structural, Microstructural and Optical Properties of Cu2ZnSnS4 (CZTS) Thin Films Prepared by Thermal Evaporation Technique
,”
Pramana J. Phys.
,
96
(
1
), p.
20
.10.1007/s12043-021-02253-3
9.
Al-Hamdani
,
N. A.
,
Al-Alawy
,
R. D.
, and
Hassan
,
S. J.
,
2014
, “
Effect of Gamma Irradiation on the Structural and Optical Properties of ZnO Thin Films
,”
Int. Org. Sci. Res. (IOSR) J. Comput. Eng.
,
16
(
1
), pp.
11
16
.10.9790/0661-16191116
10.
Ahmad
,
S.
,
Islam
,
S.
,
Nasir
,
M.
,
Asokan
,
K.
, and
Zulfequar
,
M.
,
2018
, “
Effects of Gamma-Ray Irradiation on the Optical Properties of Amorphous Se100-xHgx Thin Films
,”
J. Phys. Chem. Solids
,
117
, pp.
122
130
.10.1016/j.jpcs.2018.02.014
11.
Owens
,
A.
,
2006
, “
Semiconductor Materials and Radiation Detection
,”
J. Synchrotron Radiat.
,
13
(
2
), pp.
143
150
.10.1107/S0909049505033339
12.
Adetunji
,
G. J.
,
Shaniyi
,
J. A.
,
Alabi
,
A. B.
,
Ajo
,
J. A.
, and
Salau
,
M. A.
,
2005
, “
Cadmium Sulphide Thin Films for Application in Gamma Radiation Dosimetry
,”
Global J. Pure Appl. Sci.
,
12
(
2
), pp.
259
261
.10.4314/gjpas.v12i2.16600
13.
Rana
,
M. Y.
,
2012
, “
Gamma Radiation Induced Changes in the Optical Properties of CdTe Thin Films for Dosimetric Purposes
,”
Iraqi J. Phys.
,
10
(
17
), pp.
71
76
.https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/775
14.
Mehrabian
,
M. H.
,
Feizi
,
S.
, and
Dehaghi
,
S. M.
,
2020
, “
Cadmium Telluride Quantum Dots/Graphene Oxide/Poly Vinyl Acetate (CdTe QDs/GO/PVAc) Nanocomposite: A Novel Sensor for Real Time Gamma Radiation Detection
,”
Radiochim. Acta
,
108
(
6
), pp.
483
490
.10.1515/ract-2019-3209
15.
Kim
,
J.
,
Tanguay
,
J.
,
Cunningham
,
A.
, and
Kim
,
H.-K.
,
2020
, “
X-Ray Interaction Characteristic Functions in Semiconductor Detectors
,”
J. Instrum.
,
15
(
3
), p.
C03029
.10.1088/1748-0221/15/03/C03029
16.
Nikolopoulos
,
D.
,
Valais
,
I.
,
Michail
,
C.
,
Bakas
,
A.
,
Fountzoula
,
C.
,
Cantzos
,
D.
,
Bhattacharyya
,
D.
, et al.,
2016
, “
Radioluminescence Properties of the CdSe/ZnS Quantum Dot Nanocrystals With Analysis of Long-Memory Trends
,”
Radiat. Meas.
,
92
, pp.
19
31
.10.1016/j.radmeas.2016.06.004
17.
Wei
,
S.
,
Yang
,
M.
,
Sun
,
H.
,
Li
,
F.
,
Xiao
,
F.
,
Zou
,
J.
,
Ren
,
A.
, et al.,
2020
, “
Single Crystal CdSe X-Ray Detectors With Ultra-High Sensitivity and Low Detection Limit
,”
Am. Chem. Soc. Appl. Mater. Interfaces
,
12
(
50
), pp.
56126
56134
.10.1021/acsami.0c13567
18.
Amin
,
G. A. M.
, and
Spyrou
,
N. M.
,
2005
, “
Study of Gamma-Radiation-Induced Optical Effects in Ge–Se–Cd for Possible Industrial Dosimetric Applications
,”
Radiat. Phys. Chem.
,
72
(
4
), pp.
419
422
.10.1016/j.radphyschem.2004.03.013
19.
Mikhailik
,
V. B.
,
Galkin
,
S.
,
Kraus
,
H.
,
Mokina
,
V.
,
Hrytsak
,
A.
,
Kapustianyk
,
V.
,
Panasiuk
,
M.
,
Rudko
,
M.
, and
Rudyk
,
V.
,
2017
, “
ZnTe Cryogenic Scintillator
,”
J. Lumin.
,
188
, pp.
600
603
.10.1016/j.jlumin.2017.05.021
20.
Arshak
,
K.
, and
Korostynska
,
O.
,
2002
, “
Gamma Radiation Dosimetry Using Tellurium Dioxide Thin Film Structures
,”
Sensors
,
2
(
8
), pp.
347
355
.10.3390/s20800347
21.
Idris
,
M. M.
,
Olarinoye
,
I. O.
,
Ibrahim
,
M. T.
, and
Kolo
,
S. O.
,
2022
, “
Transparent Conducting Oxides Thin Film Dosimetry: Present and the Future
,”
J. Radiat. Nucl. Appl.
,
7
, pp.
49
58
.10.18576/jrna/070106
22.
Sen
,
S. K.
,
Manir
,
M. S.
,
Dutta
,
S.
,
Ali
,
M. H.
,
Khan
,
M. N. I.
,
Matin
,
M. A.
, and
Hakim
,
M. A.
,
2020
, “
Influence of Total Absorbed Dose of Co-60 Properties of h-MoO3 Thin Films
,”
Thin Solid Films
,
693
, p.
137700
.10.1016/j.tsf.2019.137700
23.
Flammersberger
,
H.
,
2010
, “
Experimental Study of Cu2ZnSnS4 Thin Films for Solar Cells
,”
Master’s thesis
, Institutionen för teknikvetenskaper, Department of Engineering Sciences, Uppsala Universitet, Uppsala, Sweden.https://uu.diva-portal.org/smash/get/diva2:380720/FULLTEXT01.pdf
24.
Verma
,
S.
,
Agrawal
,
V.
,
Jain
,
K.
,
Pasricha
,
R.
, and
Chand
,
S.
,
2013
, “
Green Synthesis of Nanocrystalline Cu2ZnSnS4 Powder Using Hydrothermal Route
,”
J. Nanopart.
,
2013
, pp.
1
7
.10.1155/2013/685836
25.
Su
,
Z.
,
Sun
,
K.
,
Han
,
Z.
,
Cui
,
H.
,
Liu
,
F.
,
Lai
,
Y.
,
Li
,
J.
,
Hao
,
X.
,
Liu
,
Y.
, and
Green
,
M. A.
,
2014
, “
Fabrication of Cu2ZnSnS4 Solar Cells With 5.1% Efficiency Via Thermal Decomposition and Reaction Using a Non-Toxic Sol–Gel Route
,”
J. Mater. Chem. A
,
2
(
2
), pp.
500
509
.10.1039/C3TA13533K
26.
Jiang
,
M.
, and
Yan
,
X.
,
2013
, “
Cu2ZnSnS4 Thin Film Solar Cells: Present Status and Future Prospects
,”
Solar Cells—Research and Application Perspectives
,
InTech
, Rijeka, Croatia.10.5772/50702
27.
Akcay
,
N.
,
Ataser
,
T.
,
Ozen
,
Y.
, and
Ozcelik
,
S.
,
2020
, “
Influence of Sulfurization Time on the Properties of Cu2ZnSnS4 Thin Films Deposited on Mo-Coated Sola Lime Glass Substrates by Co-Sputtering Technique
,”
Thin Solid Films
, 704, p.
138028
.10.1016/j.tsf.2020.138028
28.
Aruna-Devi
,
R.
,
Latha
,
M.
,
Velumani
,
S.
, and
Chávez-Carvayar
,
J. A.
,
2021
, “
Structural and Optical Properties of CZTS Nanoparticles Prepared by a Colloidal Process
,”
Rare Met.
,
40
(
9
), pp.
2602
2609
.10.1007/s12598-019-01288-1
29.
Obasi
,
C. O.
,
Ikhioya
,
I. L.
,
Ahmad
,
A. S.
, and
Ramalan
,
A. M.
,
2019
, “
Effect of Gamma Radiation (60CO) on the Optical Transmittance, Energy Band Gap and Absorption Coefficient of ZnSe Thin Films
,”
Int. J. Eng., Appl. Sci. Technol.
,
4
(
8
), pp.
224
228
.https://www.ijeast.com/papers/224-228,Tesma408,IJEAST.pdf
30.
Dewi
,
R.
,
Krisman
,
Zulkarnain
,
Rahmawati
,
Luqman
,
T. S.
, and
Husain
,
S.
,
2019
, “
Characterization of Optical Properties of Thin Film Ba1-xSrxTiO3 (x = 0.70; x = 0.75; and x = 0.80) Using Ultraviolet Visible Spectroscopy
,”
AIP Conf. Proc.
,
2169
, p.
060002
.10.1063/1.5132680
31.
Peksu
,
E.
, and
Karaagac
,
H.
,
2021
, “
Characterization of Cu2ZnSnS4 Thin Films Deposited by One-Step Thermal Evaporation for a Third Generation Solar Cell
,”
J. Alloys Compd.
,
862
, p.
158503
.10.1016/j.jallcom.2020.158503
32.
Marzouk
,
M. A. E. F.
, and
Hussein
,
E. M. A.
,
2019
, “
Induced Defects by Gamma Irradiation Doses on the Structure and Optical Behavior of Undoped and TiO2-, Cr2O3-, or MnO-Doped Heavy Metal Borate Glasses
,”
Appl. Phys. A
,
125
(
2
), p. 140.10.1007/s00339-019-2440-0
33.
Sudha
,
A.
,
Sharma
,
S. L.
, and
Sharma
,
S. D.
,
2017
, “
Study of Structural, Optical and Electrical Properties of Gamma Irradiated In2O3 Thin Films for Device Applications
,”
J. Mater. Sci.: Mater. Electron.
,
28
(
6
), pp.
4619
4624
.10.1007/s10854-016-6100-2
34.
Kişnişci
,
Z.
,
Özel
,
F.
,
Tuğluoğlu
,
N.
, and
Yüksel
,
Ö. F.
,
2024
, “
Structural and Optical Properties of Cu2ZnSnSe4 Nanocrystals Thin Film
,”
Opt. Quantum Electron.
,
56
(
7
), p.
1239
.10.1007/s11082-024-07136-6
35.
Alwan
,
T. J.
,
2019
, “
Effects of Gamma Irradiation on the Physical Properties of PAni.MWCNT/PMMA Films
,”
J. Phys. Stud.
,
23
(
3
), p.
3710
.10.30970/jps.23.3710
36.
Ziti
,
A.
,
Hartiti
,
B.
,
Labrim
,
H.
,
Fadili
,
S.
,
Batan
,
A.
,
Tahri
,
M.
,
Ridah
,
A.
,
Mounkachi
,
O.
,
Benyoussef
,
A.
, and
Thevenin
,
P.
,
2019
, “
Characteristics of Kesterite CZTS Thin Films Deposited by Dip-Coating Technique for Solar Cells Applications
,”
J. Mater. Sci.: Mater. Electron.
,
30
(
14
), pp.
13134
13143
.10.1007/s10854-019-01676-4
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