Gadolina doped ceria (GDC) is a promising electrolyte for intermediate temperature solid oxide fuel cells (IT-SOFC). Dense layers of this material can be economically deposited by screen printing. However, the inks for this technique generally use organic compounds that can raise health and safety issues, as well as economical issues. In order to obtain a low-cost alternative to the generally accepted organic-based ink, four different blends of binders were considered to prepare water-based GDC inks. The systems were deposited onto green NiO/GDC anodes produced by tape casting and treated at 1673 K for 4 h. By choosing the right combination of solvents and binders, it was possible to obtain a dense crack-free film of GDC from a water-based system.

1.
Mogensen
,
M.
,
Sammes
,
N. M.
, and
Tompsett
,
G. A.
, 2000, “
Physical, Chemical and Electrochemical Properties of Pure and Doped Ceria
,”
Solid State Ionics
0167-2738,
129
, pp.
63
94
.
2.
Tsoukleris
,
D. S.
,
Arabatzis
,
I. M.
,
Chatzivasiloglou
,
E.
,
Kontos
,
A. I.
,
Belessi
,
V.
,
Bernard
,
M. C.
, and
Falaras
,
P.
, 2005, “
2-Ethyl-1-Hexanol Based Screen-Printed Titania Thin Films for Dye-Sensitized Solar Cells
,”
Sol. Energy
0038-092X,
79
, pp.
422
430
.
3.
Ma
,
T.
,
Kida
,
T.
,
Akiyama
,
M.
,
Inoue
,
K.
,
Tsunematsu
,
S.
,
Yao
,
K.
,
Noma
,
H.
, and
Abe
,
E.
, 2003, “
Preparation and Properties of Nanostructured TiO2 Electrode by a Polymer Organic-Medium Screen-Printing Technique
,”
Electrochem. Commun.
1388-2481,
5
, pp.
369
372
.
4.
Hünert
,
R.
, 1997, “
New Metal Paste Technology From Starck
,”
Microeletron. J.
,
28
, pp.
6
7
.
5.
El-Molla
,
M. M.
, and
Schneider
,
R.
, 2006, “
Development of Ecofriendly Binders for Pigment Printing of All Types of Textile Fabrics
,”
Dyes Pigm.
0143-7208,
71
, pp.
130
137
.
6.
Kulicke
,
W. -M.
,
Reinhardt
,
U.
,
Fuller
,
G. G.
, and
Arendt
,
O.
, 1999, “
Characterization of the Flow Properties of Sodium Carboxymethylcellulose Via Mechanical an Optical Techniques
,”
Rheol. Acta
0035-4511,
38
, pp.
26
33
.
7.
Sanson
,
A.
,
Gardini
,
D.
,
Montanari
,
G.
,
Galassi
,
C.
, and
Roncari
,
E.
, 2006, “
Key Role of Milling in the Optimization of TiO2
Nanoinks,”
J. Mater. Res.
0884-2914,
21
, pp.
1561
1569
.
8.
Webb
,
P. A.
, and
Orr
,
C.
, 1997,
Analytical Methods in Fine Particle Technology
,
Micromeritics Instrument Corporation
,
Norcross, GA
, Chap. 7.
9.
Weast
,
R. C.
,
Selby
,
S. M.
, and
Hodgman
,
C. D.
, 1965,
CRC Handbook of Chemistry and Physics
, 46th ed.,
CRC
,
Boca Raton, FL
.
10.
Kundu
,
P. P.
,
Kundu
,
M.
,
Sinha
,
M.
,
Choe
,
S.
, and
Chattopadhayay
,
D.
, 2003, “
Effect of Alcoholic, Glycolic, and Polyester Resin Additives on the Gelation of Dilute Solution (1%) of Methylcellulose
,”
Carbohydr. Polym.
0144-8617,
51
, pp.
57
61
.
11.
Clasen
,
C.
, and
Kulicke
,
W. -M.
, 2001, “
Determination of Viscoelastic and Rheo-Optical Material Functions of Water-Soluble Cellulose Derivatives
,”
Prog. Polym. Sci.
0079-6700,
26
, pp.
1839
1919
.
12.
Zhang
,
L. M.
, and
Zhou
,
J. F.
, 2006, “
Synergistic Viscosity Characteristics of Aqueous Mixed Solutions of Hydroxypropyl- and Carboxymethyl Hydroxypropyl-Substituted Guar Gums
,”
Colloids Surf., A
0927-7757,
279
, pp.
34
39
.
13.
Zhang
,
L. M.
, 1999, “
Synergistic Blends From Aqueous Solutions of Two Cellulose Derivatives
,”
Colloid Polym. Sci.
0303-402X,
277
(
9
), pp.
886
890
.
14.
Trease
,
R. E.
, and
Dietz
,
R. L.
, 1972, “
Rheology of Pastes in Thick Films Printing
,”
Solid State Ionics
0167-2738, pp.
38
43
.
You do not currently have access to this content.