A comprehensive numerical model of an indirect internal reforming tubular Solid Oxide Fuel Cell (IIR-T-SOFC) has been developed. Two-dimensional axisymmetry of the velocity, temperature, and mass transfer fields was assumed in the model, but accommodating the peripheral nonuniformity of electric potential and electric current fields in the tubular cell for the case with internal reforming and electrochemical reactions. By using the developed model, it was examined how the thermal field and power generation characteristics of the cell are affected by gas inlet conditions and filling pattern of the reforming catalyst inside the fuel feed tube. In particular, optimization of the catalyst distribution pattern was demonstrated to be effective in the reduction of the maximum temperature and temperature gradient, in the mitigation of the possible appearance of a hot spot and therefore in making the life of a fuel cell longer with little loss of the power generation performance of the cell.

1.
Suzuki
,
K.
,
Iwai
,
H.
,
Kim
,
J. H.
,
Li
,
P. W.
, and
Teshima
,
K.
, 2002, “
Solid Oxide Fuel Cell and Micro Gas Turbine Hybrid Cycle and Related Fluid Flow and Heat Transfer
,” Keynote Paper,
Proc. 12th International Heat Transfer Conference
, 18–23 August, Grenoble, France.
2.
Suzuki
,
K.
,
Song
,
T. W.
, and
Iwai
,
H.
, 2002, “
Micro Gas Turbine—Solid Oxide Fuel Cell Hybrid System for Distributed Energy Generation
,” Invited Paper,
Proc. Int. Symposium on Distributed Energy Systems in the 21st Century
, 24–25 September, Tokyo, Japan.
3.
Dicks
,
A. L.
, 1998, “
Advances in Catalyst for Internal Reforming in High Temperature Fuel Cells
,”
J. Power Sources
0378-7753,
71
, pp.
111
122
.
4.
Ahmed
,
K.
, and
Foger
,
K.
, 2000, “
Kinetics of Internal Reforming of Methane on Ni/YSZ-based Anodes for Solid Oxide Fuel Cells
,”
Catal. Today
0920-5861,
63
, pp.
479
487
.
5.
Takeguchi
,
T.
,
Kikuchi
,
R.
,
Yano
,
T.
,
Eguchi
,
K.
, and
Murata
,
K.
, 2003, “
Effect of Precious Metal Addition to Ni-YSZ Cermet on Reforming of CH4 and Electrochemical Activity as SOFC Anode
,”
Catal. Today
0920-5861,
84
, pp.
217
222
.
6.
George
,
R. A.
, 2000, “
Status of Tubular SOFC Field Unit Demonstrations
,”
J. Power Sources
0378-7753,
86
, pp.
134
139
.
7.
Nagata
,
S.
,
Momma
,
A.
,
Kato
,
T.
, and
Kasuga
,
Y.
, 2001, “
Numerical Analysis of Output Characteristics of Tubular SOFC With Internal Reformer
,”
J. Power Sources
0378-7753,
101
, pp.
60
71
.
8.
Aguiar
,
P.
,
Chadwick
,
D.
, and
Kershenbaum
,
L.
, 2002, “
Modelling of an Indirect Internal Reforming Solid Oxide Fuel Cell
,”
Chem. Eng. Sci.
0009-2509,
57
, pp.
1665
1677
.
9.
Suzuki
,
K.
,
Li
,
P. W.
,
Nishino
,
T.
, and
Komori
,
H.
, 2002, Internal Report in Heat Transfer Laboratory, HT2002–01–01,
Kyoto University
.
10.
Li
,
P. W.
, and
Suzuki
,
K.
, 2004, “
Numerical Modeling and Performance Study of a Tubular Solid Oxide Fuel Cell
,”
J. Electrochem. Soc.
0013-4651
151
(
4
), pp.
A548
A557
.
11.
Hatchwell
,
C.
,
Sammes
,
N. M.
,
Brown
,
I. W. M.
, and
Kendall
,
K.
, 1999, “
Current Collectors for a Novel Tubular Design of Solid Oxide Fuel Cell
,”
J. Power Sources
0378-7753,
77
, pp.
64
68
.
12.
Mori
,
M.
, and
Sammes
,
N. M.
, 2002, “
Sintering and Thermal Expansion Characterization of Al-doped and Co-doped Lanthanum Strontium Chromites Synthesized by the Pechini Method
,”
Solid State Ionics
0167-2738,
146
, pp.
301
312
.
13.
Carbonell
,
R. G.
, and
Whitaker
,
S.
, 1984, “
Heat and Mass Transfer in Porous Media
,”
Fundamentals of Transport Phenomena in Porous Media
, edited by
J.
Bear
and
M. Y.
Corapcioglu
,
Martinus Nijhoff Publishers
, Dordrecht, the Netherlands, pp.
123
198
.
14.
Patankar
,
S. V.
, 1980,
Numerical Heat Transfer and Fluid Flow
(
Hemisphere Series on Computational Methods in Mechanics and Thermal Science
),
John Benjamins Publishing Co.
, Amsterdam, The Netherlands.
15.
Achenbach
,
E.
, 1994, “
Three-Dimensional and Time-Dependent Simulation of a Planar Solid Oxide Fuel Cell Stack
,”
J. Power Sources
0378-7753,
49
, pp.
333
348
.
16.
Bessette
, II,
N. F.
,
Wepfer
,
W. J.
, and
Winnick
,
J.
, 1995, “
A Mathematical Model of a Solid Oxide Fuel Cell
,”
J. Electrochem. Soc.
0013-4651,
142
(
11
), pp.
3792
3800
.
17.
Nishino
,
T.
, 2004, “
Development and Numerical Prediction of a Comprehensive Analytical Model of an Indirect-Internal-Reforming Tubular SOFC
,” Master thesis in Dept. Mechanical Engineering, Kyoto University.
18.
Lehnert
,
W.
,
Meusinger
,
J.
, and
Thom
,
F.
, 2000, “
Modelling of Gas Transport Phenomena in SOFC Anodes
,”
J. Power Sources
0378-7753,
87
, pp.
57
63
.
You do not currently have access to this content.